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Scaling and Universality in the Counterion-Condensation Transition at Charged Cylinders

机译:大学学报(自然科学)中南民族大学学报(自然科学版   带电气缸

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摘要

We address the critical and universal aspects of counterion-condensationtransition at a single charged cylinder in both two and three spatialdimensions using numerical and analytical methods. By introducing a novelMonte-Carlo sampling method in logarithmic radial scale, we are able tonumerically simulate the critical limit of infinite system size (correspondingto infinite-dilution limit) within tractable equilibration times. The criticalexponents are determined for the inverse moments of the counterionic densityprofile (which play the role of the order parameters and represent the inverselocalization length of counterions) both within mean-field theory and withinMonte-Carlo simulations. In three dimensions (3D), correlation effects(neglected within mean-field theory) lead to an excessive accumulation ofcounterions near the charged cylinder below the critical temperature(condensation phase), while surprisingly, the critical region exhibitsuniversal critical exponents in accord with the mean-field theory. In twodimensions (2D), we demonstrate, using both numerical and analyticalapproaches, that the mean-field theory becomes exact at all temperatures(Manning parameters), when number of counterions tends to infinity. For finiteparticle number, however, the 2D problem displays a series of peculiar singularpoints (with diverging heat capacity), which reflect successive de-localizationevents of individual counterions from the central cylinder. In both 2D and 3D,the heat capacity shows a universal jump at the critical point, and the energydevelops a pronounced peak. The asymptotic behavior of the energy peak locationis used to locate the critical temperature, which is also found to be universaland in accordance with the mean-field prediction.
机译:我们使用数值和分析方法,针对两个和三个空间维度中的单个带电圆柱体,探讨了抗衡离子缩合转变的关键和普遍性。通过在对数径向尺度上引入新颖的Monte-Carlo采样方法,我们能够在可控制的平衡时间内数值模拟无限大系统尺寸的临界极限(对应于无限稀释极限)。在平均场理论和蒙特卡洛模拟中,均针对反离子密度分布的反矩(其起序参数的作用并代表反离子的反局部化长度)确定了临界指数。在三个维度(3D)中,相关效应(在平均场理论中被忽略)导致低于临界温度(凝结相)的带电圆柱附近的反离子过多积累,而令人惊讶的是,临界区域表现出与均值一致的通用临界指数场理论。在二维(2D)中,我们使用数值和解析方法证明,当反离子数趋于无穷大时,平均场理论在所有温度(曼宁参数)下都变得精确。但是,对于有限粒子数,二维问题显示了一系列奇异点(具有不同的热容量),这些奇异点反映了各个抗衡离子从中心圆柱体连续发生的离域事件。在2D和3D中,热容量在临界点都显示出普遍的跃变,并且能量出现明显的峰值。能量峰值位置的渐近行为用于确定临界温度,该临界温度也被发现是通用的,并且与平均场预测一致。

著录项

  • 作者

    Naji, Ali; Netz, Roland R.;

  • 作者单位
  • 年度 2005
  • 总页数
  • 原文格式 PDF
  • 正文语种 {"code":"en","name":"English","id":9}
  • 中图分类
  • 入库时间 2022-08-20 21:08:25

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